Enkapsulasi Urea Pada Lumpur PDAM-Alginat sebagai Pupuk Lepas Lambat

  • Ismail Astar Universitas Panca Bhakti
    (ID)
  • Ida Ayu Suci Universitas Panca Bhakti
    (ID)

Abstract

Modification of sludge solid waste regional water company (PDAM) Pontianak with alginate for the application of slow-release urea fertilizer. Characterization of materials was performed with Fourier-Transform Infra-Red (FTIR) spectroscopy and scanning electron microscopy (SEM). Analysis of the FTIR spectrum obtained showed that the characteristics of the absorption band at wavelengths of 3639.89 cm-1 and 3690.9 cm-1 are characteristic of the vibration of NH2 stretching asymmetric and symmetric derived from the presence of urea. Nitrogen release tests on mud PDAM-alginate composites with concentrations of 10%, 20%, 30%, 40% and 50% for 72 consecutive hours of 12,80%, 19,33%, 4,00%, 8,39% and 6,20%. This shows that urea encapsulated mud PDAM-alginate at a concentration of 30% is the composition with the best results in holding urea encapsulated.

 

Downloads

Download data is not yet available.

References

Adzmi F, Meon S, Musa MH, Yusuf NA. 2012. Preparation, characterisation and viability of encapsulated Trichoderma harzianum UPM40 in Alginate-Montmorillonite Clay. Journal of Microencapsulation, 29(3), 205–210.

Azizah A, Irwan A, Sunardi. 2012. Sintesis dan karakterisasi polimer superabsorben berbasis selulosa dari tanaman purun tikus (Eleocharis dulcis) tercangkok akril amida (AAM). Sains dan Terapan Kimia, 6(1), 59-70.

Behin J, Nader S. 2016. Utilization of waste lignin to prepare controlled-slow release urea. International Journal Recycle Organic Waste Agriculture. DOI 10.1007/s40093-016-0139-1:1-11.

Faisol, W., Rubiyanto, D., Chuenchom L., and Is Fatimah. 2019. Alginate-Modified Saponite And Study For Ureaslow Released Fertilizer Application, Rasayan J. Chem., 12(4), 1792-1802(2019) http://dx.doi.org/10.31788/RJC.2019.1245386

Garcı´a, M.C.; Dı´ez, J.A.; Vallejo, A.; Garcı´a, L.; Cartagena, M.C. 1996. Use of Kraft Pine Lignin in Controlled Release Fertilizer Formulations, Industrial Engineering Chemical Research, 35, 245–249.

Hähndel, R. (BASF). 1997. Reply to the request on controlled-release fertilizers. Personal communication.

Irwan A., Sunardi, Annisa S. 2013. Polimer superabsorben berbasis akrilamida (AAM) tercangkok pati bonggol pisang (Musa paradisiacal). Prosiding Semirata FMIPA Universitas Lampung. (h. 45-53). Lampung.

Li A, Zhang J, Wang A. 2007. Utilization of starch and clay for the preparation of superabsorbent composite. Bioresource Technology, 98, 327–332.

Li J, Lu J, Li Y. 2009. Carboxylmethylcellulose/Bentonite composite gels: water sorption behavior and controlled release of herbicide. Journal of Applied Polymer Science, 112, 261–268.

Lubkowski, K. 2016. Environmental impact of fertilizer use and slow release of mineral nutrients as a response to this challenge. Polish Journal of Chemical Technology, 18(1), 72-79.

Maulinda, R., Damayani, M., dan Joy, B. 2017. Pengaruh Pupuk Kombinasi Urea– Zeolit - Arang Aktif (UZAA) terhadap pH, Eh, Amonium dan Nitrat pada Tanah Sawah Rancaekek, Kabupaten Bandung, Soilrens, Volume 15(2):1-8.

Mayori E., Nadia A, Fauziah A, Sunardi. 2017. Karakterisasi Biokomposit Alginat-Pati-Kaolin sebagai Kandidat Slow-Release Pupuk Urea. Prosiding Seminar Nasional Lingkungan Lahan Basah April 2018, Banjarmasin, Indonesia. Halaman 191-195

Meyer, R.C., A.R .Winter and H.H Weister. 1959. Edible protective coatings for extending the self life of poultry. Food Technology, 13: 146- 148.

Nainggolan, Ganda Darmono., Suwardi., dan Darmawan. 2009. Pola pelepasan nitrogen dari pupuk tersedia lambat (slow release fertilizer) urea-zeolit-asam humat. Prosiding Seminar Nasional Zeolit IV Bandung: 2-4 November 2009.

Ni B, Liu M, Lu S, Xie L, Wang Y. 2010. Multifunctional slow-release organic- inorganic compound fertilizer. Journal of Agricultural and Food Chemistry 58:12373–12378.

Posey, T and Hester, R.D. 1991. Developing a Biodegradable Film for Controlled Release of Fertilizer. Plastics Engineering, 50(1), 19–21

Saleh, M., Zulmanwardi, dan Pasanda, O.S. 2018. Pembuatan Pupuk SRF (slow release fertilizer) dengan Menggunakan Polimer Amilum, Prosiding Seminar Hasil Penelitian (SNP2M), Jakarta, Indonesia. 80-85.

Savana, R.T., dan Maharani, D.K. 2017. Analisis Komposisi Unsur Pupuk Lepas Lambat Kitosan-Silika-Glutaraldehid, Unesa Journal of Chemistry. Vol. 7, No. 1:21-24.

Scott, R.P.W. 1993. Silica Gel and Properties and Use in Lc, John Willey & Son, Toronto.

Styana UIF. 2010. Penggunaan metode coating campuran zeolit dan pati untuk meningkatkan keterikatan nitrogen dan kekuatan pada pupuk granul [tesis]. Yogyakarta: Universitas Gadjah Mada.

Sunardi, Irwan A, Latifah A, Istikowati WT, Haris A. 2017. Kajian pengaruh jumlah agen pengikat silang terhadap karakteristik superabsorben asam akrilat tercangkok selulosa dari alang-alang (Imperata cylindrica). Jurnal Sains dan Terapan Kimia, 11(1),15 – 23.

Swantomo, D., Rochmadi, Basuki, K. T., and Sudiyo, R. 2014. Effect of Silica Fillers on Characterization of Cellulose-Acrylamide Hydrogels Matrices as Controlled Release Agents for Urea Fertilizers. Indo. J. Chem, Vol. 14 (2): pp.116-121.

Tangboriboorant, P.; Sirichaiwat, C. 1996. Urea Fertilizer Encapsulation Using Natural Rubber Latex. Plastics, Rubber and Composites Processing and Applications, 25(7), 340–346.

Tao S, Liu J, Jin K, Qiu X, Zhang Y, Ren X, Hu S. 2011. Preparation and characterization of triple polymer-coated controlled-release urea with water-retention property and enhanced durability. Journal of Applied Polymer Science, 120, 2103–2111.

Tomaszewska M, Jarosiewicz A. 2004. Polysulfone coating with starch addition in CRF formulation. Desalination, 163, 247-252

Wen P, Wu Z, He Y, Han Y, Tong Y. 2015. Characterization of p(AA-co-AM)/Bent/Urea and its swelling and slow release behavior in a simulative soil environment. Journal Applied Polymer Science DOI: 10.1002/APP.43082:43082- 43082.

Wu L, Liu M. 2008. Preparation and properties of chitosan-coated npk compound fertilizer with controlled-release and water retention. Carbohydrate polymers, 72, 240–247.

Zou, H. Y. Ling, X. Dang, N. Yu, Y. Ling Zhang, Y, Long Zhang, and J. Dong. 2015. Solubility Characteristics and Slow-Release Mechanism of Nitrogen from Organik-Inorganik Compound Coated Urea. Hindawi Publishing Corporation International Journal of Photoenergy. Volume 2015:139-145.

Published
2022-06-07
How to Cite
Astar, I., & Ayu Suci, I. (2022). Enkapsulasi Urea Pada Lumpur PDAM-Alginat sebagai Pupuk Lepas Lambat. Al-Kimia, 10(1). https://doi.org/10.24252/al-kimia.v10i1.23740
Section
Article
Abstract viewed = 505 times