Potensi Zat Warna dari Ekstrak Etanol Kayu Sappang Sebagai KalorimetriAnion

  • Nurmala Sari STIKES Mega Rezky Makassar
    (ID)
  • Rachma Rachma Politeknik Akademi Teknik Industri Makassar
  • Santi Santi STIKES Mega Rezky Makassar

Abstract

Dye from Sappang Tree has been isolated using ethanol as a solvent. Braziline is one of the chemical compound found in the ethanol extract. The Compound can be used as anion calorimethric due to their active sites of hydroxyl and chromophore groups. Dyes from sappang tree has been tested on 10 g of several types of saturated anions (carbonate, sulfate, phosphate, cyanide, acetate, borax, nitrite, chloride, bromide, and iodide). The results of the tests show that the color of the dye from changes in carbonate, phosphate, cyanide, acetate, nitrite, and hydroxyl. Spectrophotometer UV/Vis is used to detect the limit of cyanide anion. Metanol and acetone show positive results on the dye in cyanide anion. Detection limit of braziline is 3x10-4 M. By addition of cyanide anion, the dye has detection limit at 1x10-4 M.

 

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References

Afkhami, A. & Nahid, S. (2007). A novel cyanide sensing phase based on immobilization of methyl violet on a triacetylcellulose membrane, Sensor and Actuator B, 122 (2) 437-441.

Alghiri, D. (2010), Sintesis turunan chalcone dari vanilin dan potensi penggunaannya sebagai indikator titrasi asam basa dan sensor anion, Tesis, Jurusan Kimia FMIPA UGM, Yogyakarta.

Indriani, H. (2003). Stabilitas pigmen alami kayu secang (caesalpinia sappan linn.) dalam model minuman ringan. Skripsi. Institut Pertanian, Bogor.

Marini, V., G., Torri, E., Zinmermann, L., M., & Machadoa, V., G. (2010). Anionic chromogenic chemosensor based on 4-(4-nitrobenzylideneamine)-2,6-diphenylphenol for selective detection of cyanide in acetonitrile-water mixture, ARKIVOC, 11, 146-162.

McDonagh, C., Burke, C.S. & Mac.Craith, B.D. (2008). Optical chemical sensors, Chem. Rev., 108(2), 400-422.

Reichardt, C. (1994). Solvatochromic dyes as solvent polarity indicators, Chem. Rev., 94 (8), 2319-2358.

Satheshkumar, A., Mossalamy, E.H., Manivannan, R., Parthiban, C., Al-Harbi, L. M., Kosa, S., … Elango, K.P. (2014) Anion induced azo-hydrazone tautomerism for the selective colorimetric sensing of fluoride ion, Spectrochim. Acta, Part A, 128, 798-805.

Timberlake, C.F. & Bridle P. (1983). Anthocyanins. di dalam J. Walford (ed). Developments in Food Colours. London, Applied Science Publishers LTD.

Xu, Z., Chen, X., Kim, H. N., & Yoon, J. (2010). Sensor for the optical detection of cyanide ion, Chem. Soc. Rev., 39(1), 127-137.

Zhang, C., & Suslick, K., S. (2005). A colorimetric sensor array for organics in water, J. Am. Chem. Soc., 127(33), 11548-11549.

Published
2017-12-31
How to Cite
Sari, N., Rachma, R., & Santi, S. (2017). Potensi Zat Warna dari Ekstrak Etanol Kayu Sappang Sebagai KalorimetriAnion. Al-Kimia, 5(2), 136-144. https://doi.org/10.24252/al-kimia.v5i2.3540
Section
Article
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