Kinetics Adsorption of Fe Metal using Cellulose Acetate from Palm Fronds (Borassus Flabellifer)

Kinetika Adsorpsi Logam Fe menggunakan Selulosa Asetat dari Pelepah Lontar (Borassus Flabellifer)

  • Iin Novianty Universitas Islam Negeri Alauddin Makassar
    (ID)
  • Erma UIN Alauddin Makassar
    (ID)
  • Asri Saleh UIN Alauddin Makassar
    (ID)
  • Rahmiani Gani UIN Alauddin Makassar
    (ID)
Keywords: Palm tree fronds, Cellulose Acetate, kinetics adsorption

Abstract

Lontar palm fronds (Borassus flabellifer), containing 5.27% cellulose, can be converted into cellulose acetate, which serves as an effective adsorbent for binding iron metal. The adsorption method optimizes the binding of the adsorbate to the adsorbent based on mass and contact time. This study aims to characterize the cellulose acetate derived from lontar palm fronds and evaluate its efficacy as an adsorbent for iron (Fe) metal. The production stages of cellulose acetate include cellulose isolation, synthesis of cellulose acetate, and testing of acetyl content, with a degree of substitution valued at 2.24. Fourier transform infrared (FTIR) spectroscopy and atomic absorption spectrophotometry (AAS) were employed to characterize the cellulose acetate. The optimal absorption capacity for Fe metal was achieved with an adsorbent mass of 0.06 g, resulting in an absorption efficiency of 66.39%. The optimal contact time was determined to be 90 minutes, with an absorption efficiency of 47.56%. The adsorption kinetics of cellulose acetate for iron (Fe) followed the Pseudo Second Order model, with R² = 0.9935 and k = 0.0096.

Downloads

Download data is not yet available.

References

Apriani, Rina, Taufiqur Rohmana, Kamilia Mustikasaria. 2017. Sintesis dan Karakterisasi Membran Selulosa Asetat dari Tandan Kosong Kelapa Sawit”. Riset Industri Hasil Hutan 9, no. 2: h. 91-98.

Djuned and Fauzi Muhammad. 2014. Synthesis and Characterization of Cellulose Acetat from TCF Oil Palm Empty Fruit Bunch Pulp”. Bio Resoursces 9, no. 3: h. 4710-4721.

Gaol, M Roganda L Lumban. 2013. Pembuatan Selulosa Asetat dari α -Selulosa Tandan Kosong Kelapa Sawit. Teknik Kimia USU 2, no. 3: h. 33-39.

Ischak, Netty Ino, et al. 2021. Ekstraksi dan Karakterisasi Selulosadari Limbah Kulit Kacang Tanah (Arachys hypogaea L.) sebagai Adsorben ion Logam Besi. Chem 2, no. 1: h. 27-36.

Kan, C, et al. 2013. Adsorption of Mn from Aqueous Solution Using Fe and Mn Oxide-coated Sand. Eviromental Sciences 25, no. 7: h. 1483-1491.

Khopkar S.M. 1990.“Konsep Dasar Analitik”. Jakarta: UI Press.

Nurhayati dan Rinta Kusumawati. 2014. Sintesis Selulosa Asetat Dari Limbah Pengolahan Agar (Cellulose Acetate Synthesis from Agar Processing Waste). JPB Perikanan 9, no. 2:h. 97–107.

Novia. 2015. Pengaruh Konsentrasi Natrium Hidroksida Saat Pretreatment dan Waktu Fermentasi Terhadap Kadar Bioetanol Dari Daun Nanas. Teknik Kimia 21, no. 3: h.16-26.

Saduk, Melsiani R F and Fransisko Piri Niron. 2018. Kajian Sifat Tarik Serat Pelepah Lontar dengan Singular Fiber Tensile Testing Methode. METTEK 4, no 1, h. 8-15.

Takarano, et al. 2021. Pengaruh Massa dan Waktu Adsorben Selulosa dari Kulit Jagung terhadap Konsentrasi. Teknologi 2, no. 2: h. 117-121.

Thaiyibah. 2016. Pembuatan dan Karakterisasi Membran Selulosa Asetat-PVC dari Eceng Gondok (Eichhornia Crassipes) untuk Adsorpsi Logam Tembaga (II)” Kimia Mulawarman 14, no. 1: h. 29-35.
Published
2024-06-30
How to Cite
Iin Novianty, Erma, Saleh, A., & Gani, R. (2024). Kinetics Adsorption of Fe Metal using Cellulose Acetate from Palm Fronds (Borassus Flabellifer): Kinetika Adsorpsi Logam Fe menggunakan Selulosa Asetat dari Pelepah Lontar (Borassus Flabellifer). Al-Kimia, 12(1). https://doi.org/10.24252/al-kimia.v12i1.45761
Section
Article
Abstract viewed = 253 times