Effect of Stripping Agent Type on Internal Phase Using Emulsion Liquid Membrane Method in Metal Complex Separation

  • Anita Zefanya Marchelina Purba Universitas Padjadjaran
    (ID)
  • Husen H Bahti Universitas Padjadjaran
    (ID)
  • Retna P Fauzia Universitas Padjadjaran
    (ID)
  • Uji Pratomo Universitas Padjadjaran
    (ID)
  • Santhy Wyantuti Universitas Padjadjaran
    (ID)
Keywords: complex metals, emulsion liquid membrane, internal phase, stripping agent.

Abstract

Metal complexes are formed when a metal element coordinates with a ligand through a coordinate covalent bond. Metal elements come from the transition metal group, including lanthanides and actinides, such as heavy metals and rare earth metals. Heavy metals have a high density, atomic weight, or atomic number. Rare earth metals (LTJ) comprise 15 elements lanthanides, scandium, and itrium. Complex metals are potentially hazardous to health and the environment and must be separated. Emulsion liquid membrane (ELM) is used for the separation of complex metals as it is effective and efficient. ELM involves external, membrane, and internal phases. The internal phase is important in the separation process as it carries stripping agents to pull metals from the membrane to the internal phase. The choice of stripping agent concentration in the internal phase such as HNO3, H2SO4, HCl, NaOH, and Na2CO3 affects the extraction efficiency in the separation of complexing metals using ELM. This article aims to evaluate the effect of stripping agent concentration on extraction efficiency.

Downloads

Download data is not yet available.

References

A. A. Nurcahyo, E. S. Handayani, and S. W. Widiarti. 2019. Pengolahan Limbah Cair Logam Berat Menggunakan Emulsion Liquid Membrane (ELM), Jurnal Rekayasa Kimia Dan Lingkungan, 18(2), 123–32.
Admawi, Hayder K., and Ahmed A. Mohammed. 2023. Extraction of Cadmium from Aqueous Solutions by Emulsion Liquid Membrane (ELM) Using Three Different Carriers Dissolved in a 70:30 Ratio of Sunflower Oil to Kerosene, Journal of the Indian Chemical Society, 100(9), 101081. doi: 10.1016/j.jics.2023.101081.
Ahmad, Abdul Latif, Zulfida Mohamad Hafis Mohd Shafie, Nur Dina Zaulkiflee, and Wen Yu Pang. 2019. Preliminary Study of Emulsion Liquid Membrane Formulation on Acetaminophen Removal from the Aqueous Phase, Membranes, 9(10), 133. doi: 10.3390/membranes9100133.
Ahmad, Iffat Zareen, Asad Ahmad, Heena Tabassum, and Mohammed Kuddus. 2017. Applications of Nanoparticles in the Treatment of Wastewater. Pp. 1–25 in Handbook of Ecomaterials. Cham: Springer International Publishing.
Al-Mashhadani, S. S. A., and A. H. Al-Rawi. 2020. Application of Emulsion Liquid Membrane (ELM) for the Removal of Heavy Metals from Wastewater: A Review, Journal of Environmental Chemical Engineering, 8(1), 103730.
Al-Sagheer, Adham A., Ahmed H. Daader, Hassan A. Gabr, and Elham A. Abd El-Moniem. 2017. Palliative Effects of Extra Virgin Olive Oil, Gallic Acid, and Lemongrass Oil Dietary Supplementation on Growth Performance, Digestibility, Carcass Traits, and Antioxidant Status of Heat-Stressed Growing New Zealand White Rabbits, Environmental Science and Pollution Research International, 24(7), 6807–18. doi: 10.1007/s11356-017-8396-8.
Amenaghawon, Andrew N., Chinedu L. Anyalewechi, Handoko Darmokoesoemo, and Heri Septya Kusuma. 2022. Hydroxyapatite-Based Adsorbents: Applications in Sequestering Heavy Metals and Dyes, Journal of Environmental Management, 302, 113989. doi: https://doi.org/10.1016/j.jenvman.2021.113989.
Anarakdim, Katia, Gemma Gutiérrez, Ángel Cambiella, Ounissa Senhadji-Kebiche, and María Matos. 2021. Green Emulsified Liquid Membrane for Hexavalent Chromium Extraction: Formulation and Process Optimization, Chemical Engineering and Technology, 44(6), 988–96. doi: 10.1002/ceat.202000240.
Aprilya, Ayu, Rahmadevi Rahmadevi, and Indri Meirista. 2021. Formulasi Nanoemulsi Dengan Bahan Dasar Minyak Ikan (Oleum Iecoris Aselli), Jurnal Sains Dan Kesehatan, 70(3), 1454-2331. doi: 10.25026/jsk.v3i3.309.
AYUNINGTIAS, ANDI PUTRI. 2013. PENGARUH ELEKTROLIT Na2SO4 Dan NaCl TERHADAP RECOVERY LOGAM Cu DENGAN KOMBINASI TRANSPOR MEMBRAN CAIR DAN ELEKTROPLATING MENGGUNAKAN ASAM P-t-BUTILKALIKS[4]ARENA-TETRAKARBOKSILAT SEBAGAI ION CARRIER, Skripsi, Kimia, Universitas Hasanudin, Makasar.
Azarang, Arefeh, Ahmad Rahbar-Kelishami, Reza Norouzbeigi, and Hadi Shayesteh. 2019. Modeling and Optimization of Pertraction Performance of Heavy Metal Ion from Aqueous Solutions Using M2EHPA/D2EHPA: Application of Response Surface Methodology, Environmental Technology & Innovation, 15, 100432. doi: 10.1016/J.ETI.2019.100432.
Basuki, Kris Tri, and Sudibyo Sudibyo. 2017. EMULSION LIQUID MEMBRANE EXTRACTION OF Zr AND Hf FROM ACID NITRIC USING EXTRACTANT TOPO, Jurnal Sains Dan Teknologi Nuklir Indonesia, 18(1), 25. doi: 10.17146/jstni.2017.18.1.3161.
Davoodi-Nasab, Payman, Ahmad Rahbar-Kelishami, Jaber Safdari, and Hossein Abolghasemi. 2018a. Evaluation of the Emulsion Liquid Membrane Performance on the Removal of Gadolinium from Acidic Solutions, Journal of Molecular Liquids, 262, 97–103. doi: 10.1016/j.molliq.2018.04.062.
Davoodi-Nasab, Payman, Ahmad Rahbar-Kelishami, Jaber Safdari, and Hossein Abolghasemi. 2018b. Selective Separation and Enrichment of Neodymium and Gadolinium by Emulsion Liquid Membrane Using a Novel Extractant CYANEX® 572, Minerals Engineering, 117, 63–73. doi: 10.1016/j.mineng.2017.11.008.
Elattar, Rehab H., Samah F. El-Malla, Amira H. Kamal, and Fotouh R. Mansour. 2024. Applications of Metal Complexes in Analytical Chemistry: A Review Article, Coordination Chemistry Reviews, 501, 215568. doi: 10.1016/J.CCR.2023.215568.
Gasser, M. S., N. E. El-Hefny, and J. A. Daoud. 2008. Extraction of Co(II) from Aqueous Solution Using Emulsion Liquid Membrane, Journal of Hazardous Materials, 151(2–3), 610–15. doi: 10.1016/j.jhazmat.2007.06.032.
Gheorghe, Amalia, Anicuta Stoica, and Octavian Floarea. 2008. Emulsion Liquid Membranes Stability, UPB Scientific Bulletin, Series B: Chemistry and Materials Science, 70(3), 1454-2331.
Gilson, Stephen D. 2020. 190, 191, Small Animal Soft Tissue Surgery, 154–55. doi: 10.1201/b15217-75.
Hachemaoui, Aziza, and Kamel Belhamel. 2017. Simultaneous Extraction and Separation of Cobalt and Nickel from Chloride Solution through Emulsion Liquid Membrane Using Cyanex 301 as Extractant, International Journal of Mineral Processing, 161, 7–12. doi: 10.1016/J.MINPRO.2017.02.002.
Hamzah, Baharuddin, Widya Astuti, and Rabiah Laonu. 2015. VARIASI PERBANDINGAN VOLUME FASA MEMBRAN DAN FASA INTERNAL SERTA KONSENTRASI HNO 3 DALAM FASA INTERNAL TERHADAP EKSTRAKSI ION TIMBAL ( II ) MENGGUNAKAN TEKNIK EMULSI MEMBRAN CAIR The Variation of Volume Ratio of Membran / Internal Phase and Concentration, J. Akad. Kim, 4(2), 104-109.
Hamzah, Baharuddin, Widya Astuti, and Siti Rabiah. 2015. VARIASI PERBANDINGAN VOLUME FASA MEMBRAN DAN FASA INTERNAL SERTA KONSENTRASI HNO3 DALAM FASA INTERNAL TERHADAP EKSTRAKSI ION TIMBAL ( II ) MENGGUNAKAN TEKNIK EMULSI MEMBRAN CAIR The Variation of Volume Ratio of Membran / Internal Phase And Concentration O, J. Akad. Kim, 4(2), 104-109.
Hamzah, Baharuddin, Noor Jalaluddin, Abdul Wahid Wahab, and Ambo Upe. 2012. Pengaruh Ion Kadmium(II) Dan Nikel(II) Pada Ekstraksi Ion Tembaga(II) Dengan Ekstraktan 4-Benzoil -1-Fenil-3-Metil- 2- Pirazolin-5-On Menggunakan Emulsi Membran Cair, Jurnal Natur Indonesia, 13(3), 269. doi: 10.31258/jnat.13.3.269-275.
Hirai, Takayuki, and Takuya Orikoshi. 2004. Preparation of Gd2O3:Yb, Er, and Gd2O2S: Yb, Er Infrared-to-Visible Conversion Phosphor Ultrafine Particles Using an Emulsion Liquid Membrane System, Journal of Colloid and Interface Science, 269(1), 103–8. doi: 10.1016/J.JCIS.2003.08.026.
Kakoi, Takahiko, Masahiro Goto, and Fumiyuki Nakashio. 1996. Separation of Platinum and Palladium by Liquid Surfactant Membranes Utilizing a Novel Bi-Functional Surfactant, Journal of Membrane Science, 120(1), 77–88. doi: 10.1016/0376-7388(96)00137-8.
Khadivi, Miaad, and Vahid Javanbakht. 2020. Emulsion Ionic Liquid Membrane Using Edible Paraffin Oil for Lead Removal from Aqueous Solutions, Journal of Molecular Liquids, 319, 114137. doi: 10.1016/j.molliq.2020.114137.
Kiswandono, Agung Abadi. 2014. Study on the Transport of Phenol Through Crosslinked Polyeugenol Based Polymer Inclusion Membrane ( Pim ), 1–305.
Kiswandono, Agung, Jurusan Kimia, Fakultas Mipa, and Bandar Lampung. 2016. METODE MEMBRAN CAIR UNTUK PEMISAHAN FENOL, Analit: Analytical and Environmental Chemistry 1, 1(1), 49-81.
Koller, Martin, and Hosam M. Saleh. 2018. Introductory Chapter: Introducing Heavy Metals, Heavy Metals, 71185.
Kulkarni, P. S., S. Mukhopadhyay, and S. K. Ghosh. 2009. Liquid Membrane Process for the Selective Recovery of Uranium from Industrial Leach Solutions, Industrial and Engineering Chemistry Research, 48(6), 3118-3125. doi: 10.1021/ie800819q.
Kumar, Anil, Avinash Thakur, and Parmjit Singh Panesar. 2019. Extraction of Hexavalent Chromium by Environmentally Benign Green Emulsion Liquid Membrane Using Tridodecyamine as an Extractant, Journal of Industrial and Engineering Chemistry, 70, 394–401. doi: 10.1016/j.jiec.2018.11.002.
Kumbasar, Recep Ali, and Osman Tutkun. 2008. Separation of Cobalt and Nickel from Acidic Leach Solutions by Emulsion Liquid Membranes Using Alamine 300 (TOA) as a Mobile Carrier, Desalination. 224(1-3), 201-208. doi: 10.1016/j.desal.2007.04.088.
Lakhe, Minal, Sohan A. Parbat, Bharat A. Bhanvase, and Shirish H. Sonawane. 2021. Enhanced Performance of Emulsion Liquid Membrane Prepared with Aid of Hydrodynamic Cavitation for Effective Removal of Pb (II) from Aqueous Feed Phase: Optimization Using Artificial Neutral Networks Modeling, Journal of Environmental Chemical Engineering, 9(6), 106866. doi: 10.1016/j.jece.2021.106866.
Ma, Hao, Ozan Kökkılıç, Christopher M. Marion, Ravinder S. Multani, and Kristian E. Waters. 2018. The Extraction of Nickel by Emulsion Liquid Membranes Using Cyanex 301 as Extractant, The Canadian Journal of Chemical Engineering, 96(7), 1585–96. doi: 10.1002/cjce.23100.
Meilinda, Handias, Husein H. Bahti, Anni Anggraeni, and Syulastri Effendi. 2021. Preparation of Liquid Emulsion Membranes for Separation of Gadolinium ( III ) from Samarium ( III ) with Tributyl Phosphate or Di- ( 2-Ethylhexyl ) Phosphoric Acid Extraction Based on Emulsion Stability, Chemical Sciences Journal, 12(3), 1–8.
Meilinda, Handias, Novi Noviyanti, Anni Anggraeni, Diana Hendrati, and Husein H. Bahti. 2021. Pengaruh Berbagai Parameter Ekstraksi Dalam Pemisahan Unsur Tanah Jarang Dengan Metode Emulsion Liquid Membrane (ELM), ALCHEMY Jurnal Penelitian Kimia, 17(1), 1. doi: 10.20961/alchemy.17.1.38683.1-9.
Mohammed, Ahmed A., Huda M. Selman, and Ghassan Abukhanafer. 2018. Liquid Surfactant Membrane for Lead Separation from Aqueous Solution: Studies on Emulsion Stability and Extraction Efficiency, Journal of Environmental Chemical Engineering, 6(6), 6923–30. doi: 10.1016/j.jece.2018.10.021.
Mortaheb, Hamid R., Hitoshi Kosuge, Babak Mokhtarani, Mohammad H. Amini, and Hamid R. Banihashemi. 2009. Study on Removal of Cadmium from Wastewater by Emulsion Liquid Membrane, Journal of Hazardous Materials, 165(1–3), 630–36. doi: 10.1016/j.jhazmat.2008.10.039.
Purwani, M. V, Dan Dwi, Biyantoro Pusat, Teknologi Akselerator, and Proses Bahan. 2013. EKSTRAKSI PEMISAHAN Th-Ce DARI Ce HIDROKSIDA HASIL OLAH MONASITMENGGUNAKAN MEMBRAN EMULSI CAIR DENGAN SOLVEN TBP, J.Tek. Bhn. Nukl, 9(6), 55–113.
Raji, Maliheh, Hossein Abolghasemi, Jaber Safdari, and Ali Kargari. 2017. Pertraction of Dysprosium from Nitrate Medium by Emulsion Liquid Membrane Containing Mixed Surfactant System, Chemical Engineering and Processing - Process Intensification, 120, 184–94. doi: 10.1016/J.CEP.2017.06.010.
Sabry, Rania, Azza Hafez, Maaly Khedr, and Adel El-Hassanin. 2007. Removal of Lead by an Emulsion Liquid Membrane: Part I, Desalination, 212(1–3), 165–75. doi: 10.1016/J.DESAL.2006.11.006.
El Sayed, Maysa S. 2003. Uranium Extraction from Gattar Sulfate Leach Liquor Using Aliquat-336 in a Liquid Emulsion Membrane Process, Hydrometallurgy, 68(1-3), 51-56. doi: 10.1016/S0304-386X(02)00159-7.
Septiani, Mimin, Kurniawan Santoso, and Rafdi Abdul Majid. 2018. Alternatif Pada Proses Acid Wash Terhadap Plate Electrolyzer Di Pt Kaltim Nitrate Indonesia, Journal Of Chemical Process Engineering, 03(02), 17–21.
Setyani, Rizka, Baharuddin Hamzah, and Suherman. 2016. PENGARUH ION LOGAM Cu ( II ) TERHADAP PERSEN EKSTRAKSI ION Pb ( II ) MENGGUNAKAN TEKNIK EMULSI MEMBRAN CAIR Effect of Cu ( II ) Ion Towards Percent Extraction of Pb ( II ) Using Emulsion Liquid Membrane Technique, Jurnal Akademika Kimia, 5(2):91–97.
Shokri, Amin, Parisa Daraei, and Sina Zereshki. 2020. Water Decolorization Using Waste Cooking Oil: An Optimized Green Emulsion Liquid Membrane by RSM, Journal of Water Process Engineering, 33, 101021. doi: 10.1016/J.JWPE.2019.101021.
Sujatha, S., N. Rajamohan, S. Anbazhagan, M. Vanithasri, and M. Rajasimman. 2022. Parameter Screening, Optimization and Artificial Neural Network Modeling of Cadmium Extraction from Aqueous Solution Using Green Emulsion Liquid Membrane, Environmental Technology and Innovation, 25, 102138. doi: 10.1016/j.eti.2021.102138.
Widianti, Afifah Rana, Dwi Ratna Setiani, Fauzia Salsabila, Anni Anggraeni, Uji Pratomo, and Husein H. Bahti. 2023, Pengaruh Surfaktan Terhadap Pemisahan Logam Transisi Periode Pertama Menggunakan Metode Emulsion Liquid Membrane, ALCHEMY:Journal of Chemistry, 11(1), 1–11. doi: 10.18860/al.v11i1.15020.
Wu, Shengxi, Liangshi Wang, Longsheng Zhao, Patrick Zhang, Hassan El-Shall, Brij Moudgil, Xiaowei Huang, and Lifeng Zhang. 2018. Recovery of Rare Earth Elements from Phosphate Rock by Hydrometallurgical Processes – A Critical Review, Chemical Engineering Journal. 335, 774-800.
Yang, Hsi Hsien, Shu Mei Chien, Mei Yu Lo, John Chi Wei Lan, Wen Chang Lu, and Yong Yuan Ku. 2007. Effects of Biodiesel on Emissions of Regulated Air Pollutants and Polycyclic Aromatic Hydrocarbons under Engine Durability Testing, Atmospheric Environment. 41(34), 7232-7240. doi: 10.1016/j.atmosenv.2007.05.019.
Zaheri, Parisa, and Reza Davarkhah. 2017. Rapid Removal of Uranium from Aqueous Solution by Emulsion Liquid Membrane Containing Thenoyltrifluoroacetone, Journal of Environmental Chemical Engineering, 5(4), 4064-4068. doi: 10.1016/j.jece.2017.07.076.
ZHANG, Lichang, Qianlin CHEN, Chao KANG, Xin MA, and Zunliang YANG. 2016. Rare Earth Extraction from Wet Process Phosphoric Acid by Emulsion Liquid Membrane, Journal of Rare Earths, 34(7), 717–23. doi: 10.1016/S1002-0721(16)60087-X.
Published
2024-06-30
How to Cite
Purba, A. Z. M., H Bahti, H., P Fauzia, R., Pratomo, U., & Wyantuti, S. (2024). Effect of Stripping Agent Type on Internal Phase Using Emulsion Liquid Membrane Method in Metal Complex Separation. Al-Kimia, 12(1). https://doi.org/10.24252/al-kimia.v12i1.46271
Section
Literature Studies
Abstract viewed = 157 times