Utilization of Stripping Agents in the Internal Phase for the Removal of Heavy Metal Contaminants Using Emulsion Liquid Membranes
Abstract
Heavy metals have a high density, atomic weight, or atomic number. Heavy metals are potentially hazardous to health and the environment and must be separated. Emulsion liquid membrane is a promising technique to remove heavy metal contaminants from industrial and household effluents. Emulsion liquid membrane (ELM) is used to separate heavy metals as it is effective and efficient. ELM involves external, membrane, and internal phases. The internal phase is essential in the separation process as it carries stripping agents to pull metals from the membrane to the internal phase. The choice of stripping agent concentration in the internal phase, such as HNO3, H2SO4, HCl, NaOH, and Na2CO3, affects the extraction efficiency in separating heavying metals using ELM. This article evaluates the effect of stripping agent concentration on extraction efficiency.
Downloads
References
A. A. Nurcahyo, E. S. Handayani, and S. W. Widiarti. (2019). “Pengolahan Limbah Cair Logam Berat Menggunakan Emulsion Liquid Membrane (ELM).” Jurnal Rekayasa Kimia Dan Lingkungan 18, No. 2:123–32.
Admawi, H. K., & Ahmed A. Mohammed. (2023). “Extraction of Cadmium from Aqueous Solutions by Emulsion Liquid Membrane (ELM) Using Three Different Carriers Dissolved in a 70:30 Ratio of Sunflower Oil to Kerosene.” Journal of the Indian Chemical Society 100(9):101081. doi: 10.1016/j.jics.2023.101081.
Ahmad, A. Latif, Zulfida Mohamad Hafis Mohd Shafie, Nur Dina Zaulkiflee, & Wen Yu Pang. (2019). “Preliminary Study of Emulsion Liquid Membrane Formulation on Acetaminophen Removal from the Aqueous Phase.” Membranes 9(10). doi: 10.3390/membranes9100133.
Ahmad, I. Zareen, Asad Ahmad, Heena Tabassum, & Mohammed Kuddus. (2017). “Applications of Nanoparticles in the Treatment of Wastewater.” Pp. 1–25 in Handbook of Ecomaterials. Cham: Springer International Publishing.
Al-Mashhadani, S. S. A., and A. H. Al-Rawi. 2020. “Application of Emulsion Liquid Membrane (ELM) for the Removal of Heavy Metals from Wastewater: A Review.” Journal of Environmental Chemical Engineering 8, No. 1:103730.
Al-Sagheer, Adham A., Ahmed H. Daader, Hassan A. Gabr, and Elham A. Abd El-Moniem. 2017. “Palliative Effects of Extra Virgin Olive Oil, Gallic Acid, and Lemongrass Oil Dietary Supplementation on Growth Performance, Digestibility, Carcass Traits, and Antioxidant Status of Heat-Stressed Growing New Zealand White Rabbits.” Environmental Science and Pollution Research International 24(7):6807–18. doi: 10.1007/s11356-017-8396-8.
Amenaghawon, Andrew N., Chinedu L. Anyalewechi, Handoko Darmokoesoemo, and Heri Septya Kusuma. 2022. “Hydroxyapatite-Based Adsorbents: Applications in Sequestering Heavy Metals and Dyes.” Journal of Environmental Management 302:113989. Doi: https://doi.org/10.1016/j.jenvman.2021.113989.
Anarakdim, Katia, Gemma Gutiérrez, Ángel Cambiella, Ounissa Senhadji-Kebiche, and María Matos. 2021. “Green Emulsified Liquid Membrane for Hexavalent Chromium Extraction: Formulation and Process Optimization.” Chemical Engineering and Technology 44(6):988–96. doi: 10.1002/ceat.202000240.
Aprilya, Ayu, Rahmadevi Rahmadevi, and Indri Meirista. 2021. “Formulasi Nanoemulsi Dengan Bahan Dasar Minyak Ikan (Oleum Iecoris Aselli).” Jurnal Sains Dan Kesehatan. doi: 10.25026/jsk.v3i3.309.
Ayuningtias, Andi Putri. 2013. “Pengaruh elektrolit na2so4 dan nacl terhadap recovery logam cu dengan kombinasi transpor membran cair dan elektroplating menggunakan asam p-t-butilkaliks[4]arena-tetrakarboksilat sebagai ion carrier.” Occupational Medicine.
Azarang, Arefeh, Ahmad Rahbar-Kelishami, Reza Norouzbeigi, and Hadi Shayesteh. 2019. “Modeling and Optimization of Pertraction Performance of Heavy Metal Ion from Aqueous Solutions Using M2EHPA/D2EHPA: Application of Response Surface Methodology.” Environmental Technology & Innovation 15:100432. Doi: 10.1016/J.ETI.2019.100432.
Basuki, Kris Tri, and Sudibyo Sudibyo. 2017. “Emulsion liquid membrane extraction of zr and hf from acid nitric using extractant topo.” Jurnal Sains Dan Teknologi Nuklir Indonesia 18(1):25. doi: 10.17146/jstni.2017.18.1.3161.
Davoodi-Nasab, Payman, Ahmad Rahbar-Kelishami, Jaber Safdari, and Hossein Abolghasemi. 2018a. “Evaluation of the Emulsion Liquid Membrane Performance on the Removal of Gadolinium from Acidic Solutions.” Journal of Molecular Liquids 262(2017):97–103. doi: 10.1016/j.molliq.2018.04.062.
Davoodi-Nasab, Payman, Ahmad Rahbar-Kelishami, Jaber Safdari, and Hossein Abolghasemi. 2018b. “Selective Separation and Enrichment of Neodymium and Gadolinium by Emulsion Liquid Membrane Using a Novel Extractant CYANEX® 572.” Minerals Engineering 117(July 2017):63–73. doi: 10.1016/j.mineng.2017.11.008.
Djunaidi, Muhammad Cholid, and Abdul Haris. 2003. “Pemisahan Logam Berat Menggunakan Membran Cair Berpendukung Dengan Variabel Konsentrasi Ion Logam Dan PH Fasa Umpan.” Jurnal Kimia Sains Dan Aplikasi. doi: 10.14710/jksa.6.2.1-4.
Gasser, M. S., N. E. El-Hefny, and J. A. Daoud. 2008. “Extraction of Co(II) from Aqueous Solution Using Emulsion Liquid Membrane.” Journal of Hazardous Materials 151(2–3):610–15. doi: 10.1016/j.jhazmat.2007.06.032.
Gheorghe, Amalia, Anicuta Stoica, and Octavian Floarea. (2008). “Emulsion Liquid Membranes Stability.” UPB Scientific Bulletin, Series B: Chemistry and Materials Science 70.
Gilson, Stephen D. (2020). “190, 191.” Small Animal Soft Tissue Surgery 154–55. doi 10.1201/b15217-75.Hachemaoui, Aziza, and Kamel
Belhamel. (2017). “Simultaneous Extraction and Separation of Cobalt and Nickel from Chloride Solution through Emulsion Liquid Membrane Using Cyanex 301 as Extractant.” International Journal of Mineral Processing 161:7–12. doi: 10.1016/J.MINPRO.2017.02.002.
Hamzah, Baharuddin, Widya Astuti, and Rabiah Laonu. (2015). “Variasi perbandingan volume fasa membran dan fasa internal serta konsentrasi HNO3 dalam fasa internal terhadap ekstraksi ion timbal ( II ) menggunakan teknik emulsi membran cair.” 4(May):104–9.
Hamzah, Baharuddin, Noor Jalaluddin, Abdul Wahid Wahab, and Ambo Upe. (2012). “Pengaruh Ion Kadmium(II) Dan Nikel(II) Pada Ekstraksi Ion Tembaga(II) Dengan Ekstraktan 4-Benzoil -1-Fenil-3-Metil- 2- Pirazolin-5-On Menggunakan Emulsi Membran Cair.” Jurnal Natur Indonesia 13(3):269. doi: 10.31258/jnat.13.3.269-275.
Hirai, Takayuki, and Takuya Orikoshi. (2004). “Preparation of Gd2O3:Yb, Er and Gd2O2S: Yb, Er Infrared-to-Visible Conversion Phosphor Ultrafine Particles Using an Emulsion Liquid Membrane System.” Journal of Colloid and Interface Science 269(1):103–8. doi: 10.1016/J.JCIS.2003.08.026.
Husnurrofiq, Dedy, Wahyudi Budi Sediawan, Himawan Tri, and Bayu Murti Petrus. (2021). “Distribusi Hafnium Pada Model Kesetimbangan Cair-Cair Ekstraksi Pemisahan Zirkoniumium Dan Hafnium.” Riset Dan Teknologi Terapan (RITEKTRA) 1–8.
Kakoi, Takahiko, Masahiro Goto, and Fumiyuki Nakashio. (1996). “Separation of Platinum and Palladium by Liquid Surfactant Membranes Utilizing a Novel Bi-Functional Surfactant.” Journal of Membrane Science 120(1):77–88. doi: 10.1016/0376-7388(96)00137-8.
Khadivi, Miaad, and Vahid Javanbakht. (2020). “Emulsion Ionic Liquid Membrane Using Edible Paraffin Oil for Lead Removal from Aqueous Solutions.” Journal of Molecular Liquids. doi: 10.1016/j.molliq.2020.114137.
Kiswandono, Agung Abadi. (2014). “Study on the Transport of Phenol Through Crosslinked Polyeugenol Based Polymer Inclusion Membrane ( Pim ).” 1–305.
Kiswandono, Agung, Jurusan Kimia, Fakultas Mipa, and Bandar Lampung. (2016). “Metode membran cair untuk pemisahan fenol.” Analit: Analytical and Environmental Chemistry 1.
Kulkarni, P. S., S. Mukhopadhyay, & S. K. Ghosh. (2009). “Liquid Membrane Process for the Selective Recovery of Uranium from Industrial Leach Solutions.” Industrial and Engineering Chemistry Research. doi: 10.1021/ie800819q.
Kumar, A., Avinash Thakur, & Parmjit Singh Panesar. (2019). “Extraction of Hexavalent Chromium by Environmentally Benign Green Emulsion Liquid Membrane Using Tridodecyamine as an Extractant.” Journal of Industrial and Engineering Chemistry 70:394–401. doi: 10.1016/j.jiec.2018.11.002.
Kumbasar, Recep Ali, and Osman Tutkun. (2008). “Separation of Cobalt and Nickel from Acidic Leach Solutions by Emulsion Liquid Membranes Using Alamine 300 (TOA) as a Mobile Carrier.” Desalination. doi: 10.1016/j.desal.2007.04.088.
Kurnia, Hibarkah, Sudarmono, Alvia Dwi Wahyuni, Nurmala Adistyani, and Asep Arwan Sulaeman. (2023). “Penggunaan Material Logam Di Berbagai Industri Manufaktur Indonesia: Sistematik Kajian Literatur.” Industry Xplore 8(1):220–28. doi: 10.36805/teknikindustri.v8i1.5098.
Lakhe, M., Sohan A. Parbat, B. A. Bhanvase, & Shirish H. Sonawane. (2021). “Enhanced Performance of Emulsion Liquid Membrane Prepared with the aid of Hydrodynamic Cavitation for Effective Removal of Pb (II) from Aqueous Feed Phase: Optimization Using Artificial Neutral Networks Modeling.” Journal of Environmental Chemical Engineering. Doi: 10.1016/j.jece.2021.106866.
Ma, Hao, Ozan Kökkılıç, Christopher M. Marion, Ravinder S. Multani, and Kristian E. Waters. (2018). “The Extraction of Nickel by Emulsion Liquid Membranes Using Cyanex 301 as Extractant.” The Canadian Journal of Chemical Engineering 96(7):1585–96. doi: 10.1002/cjce.23100.
Meilinda, Handias, Husein H. Bahti, Anni Anggraeni, and Syulastri Effendi. (2021). “Preparation of Liquid Emulsion Membranes for Separation of Gadolinium ( III ) from Samarium ( III ) with Tributyl Phosphate or Di- ( 2-Ethylhexyl ) Phosphoric Acid Extraction Based on Emulsion Stability.” Chemical Sciences Journal 12(Iii):1–8.
Meilinda, Handias, Novi Noviyanti, Anni Anggraeni, Diana Hendrati, and Husein H. Bahti. (2021). “Pengaruh Berbagai Parameter Ekstraksi Dalam Pemisahan Unsur Tanah Jarang Dengan Metode Emulsion Liquid Membrane (ELM).” ALCHEMY Jurnal Penelitian Kimia 17(1):1. doi 10.20961/alchemy.17.1.38683.1-9.
Mohammed, A. A., Huda M. Selman, & Ghassan Abukhanafer. (2018). “Liquid Surfactant Membrane for Lead Separation from Aqueous Solution: Studies on Emulsion Stability and Extraction Efficiency.” Journal of Environmental Chemical Engineering 6(6):6923–30. doi: 10.1016/j.jece.2018.10.021.
Mortaheb, Hamid R., Hitoshi Kosuge, Babak Mokhtarani, Mohammad H. Amini, and Hamid R. Banihashemi. 2009. “Study on Removal of Cadmium from Wastewater by Emulsion Liquid Membrane.” Journal of Hazardous Materials 165(1–3):630–36. doi: 10.1016/j.jhazmat.2008.10.039.
Purnama, Herry, Nabilah Miftachul Jannah, and Nur Hidayati. 2024. “Penghilangan Rhodamin B Dari Limbah Cair Menggunakan Pelarut Minyak Goreng Bekas Dalam Membran Cair Emulsi.” Jurnal Ilmiah Teknik Kimia 21(2):94–102.
Purwani, M. V, Dan Dwi, Biyantoro Pusat, Teknologi Akselerator, and Proses Bahan. (2013). “Ekstraksi pemisahan Th-Cedari Ce hidroksida hasil olah monasit menggunakan membran emulsi cair dengan solven TBP.” J.Tek. Bhn. Nukl 9(Juni):55–113.
Raji, Maliheh, Hossein Abolghasemi, Jaber Safdari, and Ali Kargari. (2017). “Pertraction of Dysprosium from Nitrate Medium by Emulsion Liquid Membrane Containing Mixed Surfactant System.” Chemical Engineering and Processing - Process Intensification 120:184–94. doi: 10.1016/J.CEP.2017.06.010.
Sabry, Rania, Azza Hafez, Maaly Khedr, and Adel El-Hassanin. (2007). “Removal of Lead by an Emulsion Liquid Membrane: Part I.” Desalination 212(1–3):165–75. doi: 10.1016/J.DESAL.2006.11.006.
El Sayed, Maysa S. (2003). “Uranium Extraction from Gattar Sulfate Leach Liquor Using Aliquat-336 in a Liquid Emulsion Membrane Process.” Hydrometallurgy. doi: 10.1016/S0304-386X(02)00159-7.
Septiani, Mimin, Kurniawan Santoso, and Rafdi Abdul Majid. (2018). “Alternatif Pada Proses Acid Wash Terhadap Plate Electrolyzer Di Pt Kaltim Nitrate Indonesia.” Journal Of Chemical Process Engineering 03(02):17–21.
Setyani, Rizka, Baharuddin Hamzah, and Suherman. (2016). “Pengaruh ion logam Cu ( II ) terhadap persen ekstraksi ion Pb ( II ) menggunakan teknik emulsi membran cair effect of Cu ( II ) Ion Towards Percent Extraction of Pb ( II ) Using Emulsion Liquid Membrane Technique.” Jurnal Akademika Kimia 5(2):91–97.
Shokri, Amin, Parisa Daraei, and Sina Zereshki. (2020). “Water Decolorization Using Waste Cooking Oil: An Optimized Green Emulsion Liquid Membrane by RSM.” Journal of Water Process Engineering 33:101021. Doi: 10.1016/J.JWPE.2019.101021.
Sujatha, S., N. Rajamohan, S. Anbazhagan, M. Vanithasri, and M. Rajasimman. (2022). “Parameter Screening, Optimization and Artificial Neural Network Modeling of Cadmium Extraction from Aqueous Solution Using Green Emulsion Liquid Membrane.” Environmental Technology and Innovation. doi: 10.1016/j.eti.2021.102138.
Widianti, Afifah Rana, Dwi Ratna Setiani, Fauzia Salsabila, Anni Anggraeni, Uji Pratomo, and Husein H. Bahti. (2023). “Pengaruh Surfaktan Terhadap Pemisahan Logam Transisi Periode Pertama Menggunakan Metode Emulsion Liquid Membrane.” ALCHEMY: Journal of Chemistry 11(1):1–11. doi: 10.18860/al.v11i1.15020.
Wu, Shengxi, Liangshi Wang, Longsheng Zhao, Patrick Zhang, Hassan El-Shall, Brij Moudgil, Xiaowei H., & Lifeng Zhang. (2018). “Recovery of Rare Earth Elements from Phosphate Rock by Hydrometallurgical Processes – A Critical Review.” Chemical Engineering Journal.
Yang, Hsi Hsien, Shu Mei Chien, Mei Yu Lo, John Chi Wei Lan, Wen Chang Lu, and Yong Yuan Ku. (2007). “Effects of Biodiesel on Emissions of Regulated Air Pollutants and Polycyclic Aromatic Hydrocarbons under Engine Durability Testing.” Atmospheric Environment. doi: 10.1016/j.atmosenv.2007.05.019.
Zaheri, P., & Reza Davarkhah. (2017). “Rapid Removal of Uranium from Aqueous Solution by Emulsion Liquid Membrane Containing Thenoyltrifluoroacetone.” Journal of Environmental Chemical Engineering. Doi: 10.1016/j.jece.2017.07.076.
Zhang, Lichang, Qianlin Chen, Chao Kang, Xin MA, and Zunliang Yang. (2016). “Rare Earth Extraction from Wet Process Phosphoric Acid by Emulsion Liquid Membrane.” Journal of Rare Earths 34(7):717–23. doi: 10.1016/S1002-0721(16)60087-X.
Authors who publish with this journal agree to the following terms:
1) Authors retain copyright and grant the journal right of first publication with the work simultaneously licensed under a Creative Commons Attribution License that allows others to share the work with an acknowledgement of the work's authorship and initial publication in this journal.
2) Authors are able to enter into separate, additional contractual arrangements for the non-exclusive distribution of the journal's published version of the work (e.g., post it to an institutional repository or publish it in a book), with an acknowledgement of its initial publication in this journal.
3)Authors are permitted and encouraged to post their work online (e.g., in institutional repositories or on their website) prior to and during the submission process, as it can lead to productive exchanges, as well as earlier and greater citation of published work (See The Effect of Open Access).