Synthesis of Cellulose Acetate-Polystyrene Membrane Composites from Pineapple Peel Wastes for Methylene Blue Removal
Abstract
The cellulose acetate-polystyrene or CA-PS composite membrane from pineapple peel waste for methylene blue removal has been conducted. The steps were nata de pina preparation, cellulose acetylation process, preparation, and characterization of CA-PS composite membrane. The CA-PS composite membrane was characterized using Fourier Transform Infrared (FT-IR), Scanning Electron Microscopy (SEM), tensile and strain examination, respectively. The as-synthesized CA-PS composite membrane has the characteristic of rejection ability was about 29.96% with the pore size, membrane modulus, stress and strain were 1.9 μm, 12.48 MPa, 31.91 MPa, and 2.55, respectively. In this research, CA-PS composite membrane from pineapple peel waste was successfully removed the methylene blue dye even needs improvement to enhance its capability in rejection efficiency as same as membrane characteristics.
Downloads
References
Akarsu, M., Asilturk, M., Sayilkan, F., Kiraz, N., Arpac, E., Sayilkan, H. (2006). A Novel Approach to the Hydrothermal Synthesis of Anatase Titania Nanoparticles and the Photocatalytic Degradation of Rhodamine B, Turkish Journal of Chemistry, 30, 333-343.
Amal, M.S.K., Febiyanto, Soleh, A., Afif, M. (2016). Elektrodekolorisasi Limbah Cair Pewarna Batik dengan Memanfaatkan Batang Karbon dari Limbah Baterai Bekas, Jurnal MIPA, 39 (2), 135-142.
Aprilia, L. (2009). Preparasi Produk Nata de Pina dan Aplikasi Pengikatannya Terhadap Logam Kobalt (II), Skripsi, Departemen Kimia FMIPA Institut Pertanian Bogor, Bogor.
Ayusnika, R., Gunawan, H., Ismawati, I., Nugroho, M.W., Apriliani, R.N., Widyaningsih, S. (2014). Membran Komposit CA-PS Pemisah Limbah Batik (Rhodamine B) dengan “Dead End” Membrane Reactor, Pharmacy, 11 (2), 200-214.
Badan Pusat Statistik. (2019). Statistik Tanaman Buah-Buahan dan Sayur Tahunan, Jakarta: Badan Pusat Statistik Indonesia.
Baslak, C., Arslan, G., Kus, M., Cengeloglu, Y. (2016). Removal of Rhodamine B from Water by Using CdTeSe Quantum Dot-Cellulose Membrane Composites, RSC Advances, 6, 18549-18557.
Candido, R.G., Godoy, G.G., Goncalves, A.R. (2017). Characterization and Application of Cellulose Acetate Synthesized from Sugarcane Bagasse, Carbohydrate Polymers, 167, 280-289.
Cowd, M.A. (1982). Polymer Synthesis, London: J. Murray.
Dhananasekaran, S., Palanivel, R., Pappu, S. (2016). Adsorption of Methylene Blue, Bromophenol Blue, and Coomassie Brilliant Blue by α-Chitin Nanoparticles, Journal of Advanced Research, 7, 113-124.
El-Din, L.A.N., El-Gendi, A., Ismail, N., Abed, K.A., Ahmed, A.I. (2015). Evaluation of Cellulose Acetate Membrane with Carbon Nanotubes Additives, Journal of Industrial and Engineering Chemistry, 26, 259-264.
Febiyanto, Eliani, I.V., Riapanitra, A., Sulaeman, U. (2016). Synthesis and Visible Light Photocatalytic Properties of Iron Oxide-Silver Orthophosphate Composites, AIP Conference Proceedings, 1725, 1-6.
Febiyanto, F., Soleh, A., Amal, M.S.K., Afif, M., Sewiji, S., Riapanitra, A., Sulaeman, U. (2019). Facile Synthesis of Ag3PO4 Photocatalyst with Varied Ammonia Concentration and Its Photocatalytic Activities for Dye Removal, Bulletin of Chemical Reaction Engineering & Catalysis, 14 (1), 42-50.
Goetz, L.A., Jalvo, B., Rosal, R., Mathew, A.P. (2016). Superhydrophilic Anti-Fouling Electrospun Cellulose Acetate Membranes Coated with Chitin Nanocrystals for Water Filtration, Journal of Membrane Science, 510, 238-248.
Hameed, B.H., Ahmad, A.L., Latiff, K.N.A. (2007). Adsorption of Basic Dye (Methylene Blue) onto Activated Carbon Prepared from Rattan Sawdust, Dyes and Pigments, 75, 143-149.
Ikhsani, I.Y., Santosa, S.J., Rusdiarso, B. (2016). Comparative Study of Ni-Zn LHS and Mg-Al LDH Adsorbents of Navy Blue and Yellow F3G Dye, Indonesian Journal of Chemistry, 16 (1), 36-44.
Juansah, J., Dahlan, K., Huriati, F. (2009). Peningkatan Mutu Sari Buah Nanas dengan Memanfaatkan Sistem Filtrasi Aliran Dead-End dari Membran Selulosa Asetat, Makara Sains, 13 (1), 94-100.
Kamal, H., Abd-Elrahim, F.M., Lotfy, F. (2014). Characterization and Some Properties of Cellulose Acetate-Co-Polyethylene Oxide Blends Prepared by the Use of Gamma Irradiation, Journal of Radiation Research and Applied Sciences, 7, 146-153.
Khosravi, R., Fazlzadehdavil, M., Barikbin, B., Hossini, H. (2015). Electro-decolorization of Reactive Red 198 from Aqueous Solutions Using Aluminum Electrodes System: Modeling and Optimization of Operation Parameters, Desalination and Water Treatment, 54 (11), 3152-3160.
Lin, Y., Ye, W., Baltaru, M.-C., Tang, Y.P., Bernstein, N.J., Gao, P., Balta, S., Vlad, M., Volodin, A., Sotto, A., Luis, P., Zydney, A.L., der Bruggen, B.V. (2016). Tight Ultrafication Membranes for Enhanced Separation of Dyes and Na2SO4 During Textile Wastewater Treatment, Journal of Membrane Science, 514, 217-228.
Lindu, M., Puspitasari, T., Ismu, E. (2010). Sintesis dan Karakterisasi Selulosa Asetat dari Nata de Coco Sebagai Bahan Baku Membran Ultrafikasi, Jurnal Sains Materi Indonesia, 12 (1), 17-23.
Lismeri, L., Zari, P.M., Novarani, T., Darni, Y. (2016). Sintesis Selulosa Asetat dari Limbah Batang Ubi Kayu, Jurnal Rekayasa Kimia dan Lingkungan, 11 (2), 82-91.
Masaoka, S., Ohe, T., Sakota, N. (1993). Production of Cellulose from Glucose by Acetobacter xylinum, Journal of Fermentation and Bioengineering, 75, 18-22.
Meenakshi, P., Noorjahan, S.E., Rajini, R., Venkateswarlu, U., Rose, C., Sastry, T.P. (2002). Mechanical and Microstructure Studies on the Modification of CA Film by Blending with PS, Bulletin of Materials Science, 25, 25-29.
Mulder, M. (1996). Basic Principles of Membrane Technology, 2nd Edition, Netherland: Kluwer Academic Publisher.
Nair, S.S., Mathew, A.P. (2017). Porous Composite Membranes Based on Cellulose Acetate and Cellulose Nanocrystals via Electrospinning and Electrospraying, Carbohydrate Polymers, 175, 149-157.
Pandele, A.M., Neacsu, P., Cimpean, A., Staras, A.I., Miculescu, F., Iordache, A., Voicu, S.I., Thakur, V.K., Toader, O.D. (2018). Cellulose Acetate Membranes Functionalized with Resveratrol by Covalent Immobilization for Improved Osseointegration, Applied Surface Science, 438, 2-13.
Putri, T.P. (2006). Ciri Membran Selulosa Berpori dari Sari Kulit Nanas, Skripsi, Departemen Kimia FMIPA Institut Pertanian Bogor, Bogor.
Rahmawati, F., Fadillah, I., Mudjijono, M. (2017). Composite of Nano-TiO2 with Cellulose Acetate Membrane from Nata de Coco (Nano-TiO2/CA(NDC)) for Methyl Orange Degradation, Journal of Materials and Environmental Sciences, 8 (1), 287-297.
Rahmawati, S. (2007). Kajian Mikrostruktur Membran Komposit Seluosa Asetat Polistirena Berbahan Dasar Limbah Tahu, Skripsi, Departemen Kimia FMIPA Institut Pertanian Bogor, Bogor.
Rosdi, N.H., Kanafi, N.M., Rahman, N.A. (2018). Preparation and Thermal Properties of Cellulose Acetate/Polystyrene Blend Nanofibers via Electrospinning Technique, Pertanika J. Sci. & Technol., 26 (3), 979-990.
Scoot, K., Hughes, R. (1996). Industrial Membrane Separation Technology, London: Blackie Academic and Professional.
Soemantri, R.U. (2003). Pengaruh Penambahan Formamide dan Lama Penguapan Pelarut (Aseton) Terhadap Membran Selulosa Asetat, Skripsi, Fakultas Teknologi Pertanian Institut Pertanian Bogor, Bogor.
Souhoka, F.A., Latupeirissa, J. (2018). Sintesis dan Karakterisasi Selulosa Asetat (CA), Indonesian Journal of Chemical Research, 5 (2), 58-62.
Subramani, S.E., Thinakaran, N. (2017). Isotherm, Kinetic and Thermodynamic Studies on the Adsorption Behavior of Textile Dyes onto Chitosan, Process Safety and Environmental Protection, 106, 1-10.
Sulaeman, U., Febiyanto, F., Yin, S., Sato, T. (2016). The Highly Active Saddle-like Ag3PO4 Photocatalyst Under Visible Light Irradiation, Catalysis Communications, 85, 22-25.
Syamsu, K., Kuryani, T. (2014). Pembuatan Biofilm Selulosa Asetat dari Selulosa Mikrobial Nata de Cassava, E-Jurnal Agroindustri Indonesia, 3 (1), 126-133.
Vadivelan, V., Kumar, K.V. (2005). Equilibrium, Kinetics, Mechanism, and Process Design for the Sorption of Methylene Blue onto Rice Husk, Journal of Colloid and Interface Science, 286, 90-100.
Copyright (c) 2019 Febiyanto Febiyanto
This work is licensed under a Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International License.
Authors who publish with this journal agree to the following terms:
1) Authors retain copyright and grant the journal right of first publication with the work simultaneously licensed under a Creative Commons Attribution License that allows others to share the work with an acknowledgement of the work's authorship and initial publication in this journal.
2) Authors are able to enter into separate, additional contractual arrangements for the non-exclusive distribution of the journal's published version of the work (e.g., post it to an institutional repository or publish it in a book), with an acknowledgement of its initial publication in this journal.
3)Authors are permitted and encouraged to post their work online (e.g., in institutional repositories or on their website) prior to and during the submission process, as it can lead to productive exchanges, as well as earlier and greater citation of published work (See The Effect of Open Access).