Determination of Zirconium(IV) Based on Flow Injection Analysis with The Xylenol Orange As A Complexing
Abstract
The development of spectrophotometry method based on Flow Injection Analysis (FIA) to determine Zr(IV) in tin ore accompanying mineral has been done using xylenol orange as complexing agent. The complex between Zr(IV) and xylenol orange 0,05% was formed at pH 2 (1:1). The complex formed having maximum absorbance at wavelength 554 nm. The mineral decomposition has been done by fusion method using Na2CO3 and Na2O2 as fluxs for open system and the close system decomposition using HNO3, HClO4 and HF as solvents. FIA-spectrophotometry that has been developed was able to show good analytical performance, with precision of %KV not more than 5% at concentration level mg/L, was 3,98%, with sensitivity was 2,79 ppm and the detection limits of calculated (S/N = 3) was 0,21 ppm. This method has been aplicated for analyzing Zr(IV) in zircon mineral sample with analysis result 20,26% of ZrO2 and recovery percentage was 100,7%.
Downloads
References
Gasik., M. 2013 Technology of Zirconium Ferroalloys. Twelfth Ed. Elsevier. doi:10.1016/B978-0-08-097753-9.00016-2
Renganathan., G, Tanneru., N, Madurai SL. 2018. Orthopedical and Biomedical Applications of Titanium and Zirconium Metals. Elsevier Ltd. doi:10.1016/B978-0-08-102205-4.00010-4.
Parissi-Poulou., M, Panderi., I. 1999. Determination of Hyoscine N-Butyl-Bromide, Lidocaine Hydrochloride, And Paracetamol In Injection Forms Using Solid-Phase Extraction, High-Performance Liquid Chromatography, And UV-Vis Spectrophotometry. J Liq Chromatogr Relat Technol. 22(7):1055-1068. doi:10.1081/JLC-100101717
Ali., KJ, Kadoomm., M.R, Ali J. 2018. Determination of Zinc (II) Ion Using Dithizone by Flow Injection and Sequential Injection Techniques. tsijournals .16(II):1-18.
Rustiah., W, Noor., A, Maming, Lukman., M, Nurfadilah. Recent Analysis of Carbon, Nitrogen, and Lignin Phenol Compositions in The Suspended Particulate Matters at Spermonde Archipelago, South Sulawesi, Indonesia. Environ Nat Resour J. 2020;18(2):124-133. doi:10.32526/ennrj.18.2.2020.12
Armagan., F, Soylak., M, Elci., L, Dogan., M. 2002. Solid Phase Extraction of Some Metal Ions on Diaion-20 Resin Prior to Flame Atomic Absorption Spectrometric Analysis. J Trace Microprobe Tech. 20(1):15-27. doi:10.1081/TMA-120002457
Saracoglu., S, Soylak., M, Elci., L. 2002. On-Line Solid Phase Extraction System for Chromium Determination in Water Samples by Flow Injection-Flame Atomic Absorption Spectrometry. Anal Lett. 35(9):1519-1530. doi:10.1081/AL-120006727
Chiba., R, Soukura., M, Tatsuta., S. Solid-Phase Extraction and Determination of Sulpiride in Human Serum by High Performance Liquid Chromatography Using Electrogenerated Chemiluminescence Detection. Anal Lett. 2011;44(9):1559-1569. doi:10.1080/00032719.2010.520388
Tang., M., Li L, Zhong., Q. 2014. Determination of Herbicides in Soil by Dispersive Solid-Phase Extraction, Dispersive Liquid–Liquid Microextraction, and High-Performance Liquid Chromatography. Anal Lett. 47(18):2871-2881. doi:10.1080/00032719.2014.926552
Yang., L, Li., Y, Xj G, Ma., X, Yan., Q. 2013. Comparison of Dry Ashing, Wet Ashing and Microwave Digestion for Determination of Trace Elements in Periostracum Serpentis and Periostracum Cicadae by ICP-AES. J Chil Chem Soc. 58(3):1876-1879. doi:10.4067/S0717-97072013000300018
Chadijah., S, Rustiah., WO, Munir., MID. 2018. Determination of the optimum concentration cellulose baggase in making film bioplastic. J Phys Conf Ser. 979(1). doi:10.1088/1742-6596/979/1/012026
De Oliveira., E. 2013. Sample Preparation for Atomic Spectroscopy: Evolution and future trends. J Braz Chem Soc. 14(2):174-182.
Pikkemaat., J, Wegh., R, Lamerichs., R. 2007. Targeted ultrasound contrast agent for molecular imagingof inflammation in high-shear flow. Contrast Media Mol Imaging. 2(5):229–239. doi:10.1002/cmmi
Abdeldaim., DT, Mansour., FR. 2018. Micelle-enhanced flow injection analysis. Rev Anal Chem. 37(3):1-17. doi:10.1515/revac-2017-0009
McKelvie., ID. 2008. Principles of Flow Injection Analysis. Vol 54. Elsevierdoi:10.1016/S0166-526X(08)00604-1.
Li Y, Yu P, Wang Ql. 2016. Determination of Anabolic Hormones in Porcine Hair by High-Performance Liquid Chromatography–Mass Spectrometry. Anal Lett. 49(18):2895-2906. doi:10.1080/00032719.2016.1167218
Safavi., A, Haghighi., B, Peiravian., F. 2003. Flow Injection Analysis of Sulfide by Gas Phase Molecular Absorption UV/Vis Spectrometry. Anal Lett. 36(2):479-492. doi:10.1081/AL-120017704
Yapar., D, Dal., AG, Tuncel., M, Uysal., ÜD. 2004. Validated Method for The Determination Of Deflazacort By A Flow-Injection Analysis With UV Detection: Application to pharmaceutical formulations. J Liq Chromatogr Relat Technol. 27(16):2593-2601. doi:10.1081/JLC-200028408
Noroozifar., M, Khorasani-Motlagh., M, Akbari., R. 2007. Application of Pneumatic Flow Injection-Tandem Spectrometer System for Chromium Speciation. J Autom Methods Manag Chem. 2007;2007. doi:10.1155/2007/34373
Trenggamayunelgi., FS, Sulistyarti., H, Retnowati., R. 2019. Development of Flow Injection-Spectrophotometry Method for Hydroquinone Determination Based on The Formation of Blue Starch-Iodine Complex. IOP Conf Ser Mater Sci Eng. 546(3). doi:10.1088/1757-899X/546/3/032031
Silva., MF, Tóth., I V., Rangel., AOSS. 2006. Determination of mercury in fish by cold vapor atomic absorption spectrophotometry using a multicommuted flow injection analysis system. Anal Sci. 2006;22(6):861-864. doi:10.2116/analsci.22.861
Ramkumar., J, Chandramouleeswaran., S. 2017. Flow Injection Analysis of Iron in Presence of Uranium. Int J Anal Tech. 3(1):1-5. doi:10.15226/2577-7831/3/1/00112
Potts, P.J., A Handbook of Silicate Rocks Analysis, Blackie Academic and Profesional. 1985, 47-75.
Rustiah., W, Noor A, Lukman., M. 2019. Distribution Analysis of Nitrate and Phosphate in Coastal Area: Evidence from Pangkep River , South Sulawesi. 7(1):9-17. doi:10.20956/ijas.v7i1.1835
Yu., Z, Wang., J, Zhou., N, Zhao., C, Qiu., J. 2013. A highly sensitive method for quantitative determination of L-amino acid oxidase activity based on the visualization of ferric-xylenol orange formation. PLoS One. 8(12). doi:10.1371/journal.pone.0082483
Authors who publish with this journal agree to the following terms:
1) Authors retain copyright and grant the journal right of first publication with the work simultaneously licensed under a Creative Commons Attribution License that allows others to share the work with an acknowledgement of the work's authorship and initial publication in this journal.
2) Authors are able to enter into separate, additional contractual arrangements for the non-exclusive distribution of the journal's published version of the work (e.g., post it to an institutional repository or publish it in a book), with an acknowledgement of its initial publication in this journal.
3)Authors are permitted and encouraged to post their work online (e.g., in institutional repositories or on their website) prior to and during the submission process, as it can lead to productive exchanges, as well as earlier and greater citation of published work (See The Effect of Open Access).