Determination of Zirconium(IV) Based on Flow Injection Analysis with The Xylenol Orange As A Complexing

  • Waode Rustiah Politeknik Kesehatan Muhammadiyah Makassar
    (ID)
  • Sulistyani Sulistyani Universitas Negeri Yogyakarta
    (ID)

Abstract

The development of spectrophotometry method based on Flow Injection Analysis (FIA) to determine Zr(IV) in tin ore accompanying mineral has been done using xylenol orange as complexing agent. The complex between Zr(IV) and xylenol orange 0,05% was formed at pH 2 (1:1). The complex formed having maximum absorbance at wavelength 554 nm. The mineral decomposition has been done by fusion method using Na2CO3 and Na2O2 as fluxs for open system and the close system decomposition using HNO3, HClO4 and HF as solvents. FIA-spectrophotometry that has been developed was able to show good analytical performance, with precision of %KV not more than 5% at concentration level mg/L, was 3,98%, with sensitivity was 2,79 ppm and the detection limits of calculated (S/N = 3) was 0,21 ppm. This method has been aplicated for analyzing Zr(IV) in zircon mineral sample with analysis result 20,26% of ZrO2 and recovery percentage was 100,7%.

 

Downloads

Download data is not yet available.

References

Gasik., M. 2013 Technology of Zirconium Ferroalloys. Twelfth Ed. Elsevier. doi:10.1016/B978-0-08-097753-9.00016-2

Renganathan., G, Tanneru., N, Madurai SL. 2018. Orthopedical and Biomedical Applications of Titanium and Zirconium Metals. Elsevier Ltd. doi:10.1016/B978-0-08-102205-4.00010-4.

Parissi-Poulou., M, Panderi., I. 1999. Determination of Hyoscine N-Butyl-Bromide, Lidocaine Hydrochloride, And Paracetamol In Injection Forms Using Solid-Phase Extraction, High-Performance Liquid Chromatography, And UV-Vis Spectrophotometry. J Liq Chromatogr Relat Technol. 22(7):1055-1068. doi:10.1081/JLC-100101717

Ali., KJ, Kadoomm., M.R, Ali J. 2018. Determination of Zinc (II) Ion Using Dithizone by Flow Injection and Sequential Injection Techniques. tsijournals .16(II):1-18.

Rustiah., W, Noor., A, Maming, Lukman., M, Nurfadilah. Recent Analysis of Carbon, Nitrogen, and Lignin Phenol Compositions in The Suspended Particulate Matters at Spermonde Archipelago, South Sulawesi, Indonesia. Environ Nat Resour J. 2020;18(2):124-133. doi:10.32526/ennrj.18.2.2020.12

Armagan., F, Soylak., M, Elci., L, Dogan., M. 2002. Solid Phase Extraction of Some Metal Ions on Diaion-20 Resin Prior to Flame Atomic Absorption Spectrometric Analysis. J Trace Microprobe Tech. 20(1):15-27. doi:10.1081/TMA-120002457

Saracoglu., S, Soylak., M, Elci., L. 2002. On-Line Solid Phase Extraction System for Chromium Determination in Water Samples by Flow Injection-Flame Atomic Absorption Spectrometry. Anal Lett. 35(9):1519-1530. doi:10.1081/AL-120006727

Chiba., R, Soukura., M, Tatsuta., S. Solid-Phase Extraction and Determination of Sulpiride in Human Serum by High Performance Liquid Chromatography Using Electrogenerated Chemiluminescence Detection. Anal Lett. 2011;44(9):1559-1569. doi:10.1080/00032719.2010.520388

Tang., M., Li L, Zhong., Q. 2014. Determination of Herbicides in Soil by Dispersive Solid-Phase Extraction, Dispersive Liquid–Liquid Microextraction, and High-Performance Liquid Chromatography. Anal Lett. 47(18):2871-2881. doi:10.1080/00032719.2014.926552

Yang., L, Li., Y, Xj G, Ma., X, Yan., Q. 2013. Comparison of Dry Ashing, Wet Ashing and Microwave Digestion for Determination of Trace Elements in Periostracum Serpentis and Periostracum Cicadae by ICP-AES. J Chil Chem Soc. 58(3):1876-1879. doi:10.4067/S0717-97072013000300018

Chadijah., S, Rustiah., WO, Munir., MID. 2018. Determination of the optimum concentration cellulose baggase in making film bioplastic. J Phys Conf Ser. 979(1). doi:10.1088/1742-6596/979/1/012026

De Oliveira., E. 2013. Sample Preparation for Atomic Spectroscopy: Evolution and future trends. J Braz Chem Soc. 14(2):174-182.

Pikkemaat., J, Wegh., R, Lamerichs., R. 2007. Targeted ultrasound contrast agent for molecular imagingof inflammation in high-shear flow. Contrast Media Mol Imaging. 2(5):229–239. doi:10.1002/cmmi

Abdeldaim., DT, Mansour., FR. 2018. Micelle-enhanced flow injection analysis. Rev Anal Chem. 37(3):1-17. doi:10.1515/revac-2017-0009

McKelvie., ID. 2008. Principles of Flow Injection Analysis. Vol 54. Elsevierdoi:10.1016/S0166-526X(08)00604-1.

Li Y, Yu P, Wang Ql. 2016. Determination of Anabolic Hormones in Porcine Hair by High-Performance Liquid Chromatography–Mass Spectrometry. Anal Lett. 49(18):2895-2906. doi:10.1080/00032719.2016.1167218

Safavi., A, Haghighi., B, Peiravian., F. 2003. Flow Injection Analysis of Sulfide by Gas Phase Molecular Absorption UV/Vis Spectrometry. Anal Lett. 36(2):479-492. doi:10.1081/AL-120017704

Yapar., D, Dal., AG, Tuncel., M, Uysal., ÜD. 2004. Validated Method for The Determination Of Deflazacort By A Flow-Injection Analysis With UV Detection: Application to pharmaceutical formulations. J Liq Chromatogr Relat Technol. 27(16):2593-2601. doi:10.1081/JLC-200028408

Noroozifar., M, Khorasani-Motlagh., M, Akbari., R. 2007. Application of Pneumatic Flow Injection-Tandem Spectrometer System for Chromium Speciation. J Autom Methods Manag Chem. 2007;2007. doi:10.1155/2007/34373

Trenggamayunelgi., FS, Sulistyarti., H, Retnowati., R. 2019. Development of Flow Injection-Spectrophotometry Method for Hydroquinone Determination Based on The Formation of Blue Starch-Iodine Complex. IOP Conf Ser Mater Sci Eng. 546(3). doi:10.1088/1757-899X/546/3/032031

Silva., MF, Tóth., I V., Rangel., AOSS. 2006. Determination of mercury in fish by cold vapor atomic absorption spectrophotometry using a multicommuted flow injection analysis system. Anal Sci. 2006;22(6):861-864. doi:10.2116/analsci.22.861

Ramkumar., J, Chandramouleeswaran., S. 2017. Flow Injection Analysis of Iron in Presence of Uranium. Int J Anal Tech. 3(1):1-5. doi:10.15226/2577-7831/3/1/00112

Potts, P.J., A Handbook of Silicate Rocks Analysis, Blackie Academic and Profesional. 1985, 47-75.

Rustiah., W, Noor A, Lukman., M. 2019. Distribution Analysis of Nitrate and Phosphate in Coastal Area: Evidence from Pangkep River , South Sulawesi. 7(1):9-17. doi:10.20956/ijas.v7i1.1835

Yu., Z, Wang., J, Zhou., N, Zhao., C, Qiu., J. 2013. A highly sensitive method for quantitative determination of L-amino acid oxidase activity based on the visualization of ferric-xylenol orange formation. PLoS One. 8(12). doi:10.1371/journal.pone.0082483

Published
2021-12-31
How to Cite
Rustiah, W., & Sulistyani, S. (2021). Determination of Zirconium(IV) Based on Flow Injection Analysis with The Xylenol Orange As A Complexing. Al-Kimia, 9(2), 141-150. https://doi.org/10.24252/al-kimia.v9i2.23638
Section
Article
Abstract viewed = 311 times